Product ID:CLC-700/800 STARTER BLACK, F42-0402
MSDS Date:02/01/1994
FSC:6850
NIIN:00N063308
MSDS Number: BYWSV

CANON USA INC

ONE CANON PLAZA
LAKE SUCCESS, NY 11042
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 516-328-5600

Preparer: JOSEPH PALMERI

Cage: 1BA63

CANON USA INC

LAKE SUCCESS, NY 11042 US

Telephone: 516-328-5600

Cage: 1BA63

IRON (III) OXIDE; (FERRITE POWDER MIXTURE W/INGS 2 & 3)

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: 90-95%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3 FUME (FE)

ZINC OXIDE (SARA 313) (CERCLA)

CAS: 1314-13-2

RTECS: ZH4810000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

COPPER OXIDE; (CUPRIC OXIDE)

CAS: 1317-38-0

RTECS: GL7900000

OSHA PEL 1 MG/M3 (CU)

ACGIH TLV: 1 MG/M3 (CU)

BISPHENOL A PROPYLENE OXIDE FUMARATE; (POLYESTER RESIN)

CAS: 39382-25-7

Fraction By Weight: 3-10%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <1%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

COPPER; (COPPER & COMPOUNDS) (SARA 313) (CERCLA)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 15% MAX

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ZINC; (ZINC & COMPOUNDS) (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 15% MAX

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CONTAINING PRODUCT OR DERIVED FROM PRODUCT SHOULD BE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) >5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR REC
HNDLG. EYE:NO SPECIFIC HAZS KNOWN. MAY CAUSE TRANSIENT IRRIT. NOT
CLASSIFIED AS IRRIT ACCORDING TO OSHA HAZ COMMUNICATION STD (HCS).
SKIN:EXPECTED TO BE LOW HAZ FO R REC HNDLG. NOT CLASSIFIED AS
IRRIT, ACCORDING TO HCS. INGEST:EXPECTED TO BE LOW INGEST HAZ. DATA
FROM(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SIMILAR TONER MATLS. CHRONIC:BASED
UPON AVAIL DATA, HUMAN EXPOS TO TONER HAS BEEN SHOWN TO CAUSE MIN
RESP TRACT IRRIT AS MAY OCCUR W/LG AMTS OF ANY NONTOX DUSTS. RSLTS
OF ONE ANIMAL STUDY WHE RE RATS INHALED TONER THAT WAS TEN TIMES
MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER WERE OBSERVED AT
HIGHER (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS
PERSIST. EYES:ANY MATERIAL THAT CONTACTS EYE SHOULD BE WASHED OUT
IMMEDIATELY W/WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION
IF SYMPT OMS OCCUR. SKIN:WASH W/SOAP & WATER. GET MEDICAL ATTENTION
IF SYMPTOMS OCCUR. INGEST:DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL
ATTENTION.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES.

Spill Release Procedures:SWEEP MATL ONTO PAPER & PLACE IN FIBER CARTON.
SWEEP/SCOOP UP & REMOVE. FLUSH RESIDUAL SPILL AREA W/WATER. THIS
MATL HAS NOT BEEN TESTED FOR ENVIRON EFTS. IN SPILL SITUATION THIS
MATL MAY BE VISUALLY UNPLEASANT; HOWEVER, IT IS NOT
EXPECTEDTO(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:LOW HAZARD FOR RECOMMENDED HANDLING.
GOOD INDUS HYGIENE PRACTICE SHOULD BE FOLLOWED WHICH INCLS
PREVENTING EYE CONT, MINIMIZING SKIN CONT, INHALATION.
Other Precautions:KEEP FROM CONT W/OXIDIZING MATLS. MINIMIZE DUST
GENERATION & ACCUM. REFER TO PAMPHLET NO.654, "PREVENTION OF FIRE &
DUST EXPLOSIONS IN CHEM, DYE, PHARMACEUTICAL & PLASTICS
INDUSTRIES." KEEP CNTNR CLOS ED. AVOID BRTHG DUST. USE W/ADEQ VENT.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE SHOULD BE NEEDED.
Ventilation:GOOD VENT (TYPICALLY 4-6 ROOM VOLS PER HR) SHOULD BE USED.
VENT RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:LEVELS A SLIGHT DEGREE OF LUNG FIBROSIS WAS OBSERVED
DUE TO EXCESSIVE AMTS OF DUST RETAINED IN LUNGS FOR PRLNG INTERVAL.
SPILL PROC:CAUSE ANY ADVERSE ENVIRON EFTS. WASTE DISP METH:LIST
ING/CHARACT. HOWEVER, UNDER RCRA, IT ISRESPONSIBILITY OF END-USER
TO DETERMINE AT TIME OF DISP, WHETHER MATL (ING 8)

Spec Gravity:4-4.5 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID BLACK POWDER; SLIGHT PLASTIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE
& POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE OR OXIDES OF
NITROGEN.

Waste Disposal Methods:INCIN/LANDFILL, CAN BE INCIN WHEN IN COMPLIANCE
W/LOC REGS. DISCHARGE, TREATMENT/DISP MAY BE SUBJECT TO NATIONAL,
STATE/LOC LAWS. EMPTY RECEPTACLE MAY BE RECYCLED. IF DISCARDED IN
ITS PURCHASED FORM, THIS PROD WOULD NOT BE HAZ WASTE
EITHERBY(SUPDAT)

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particular situation.